Before They Were Famous Guess Who?

The youngest of five siblings, this brainiac actress was a 4.0 student at her all-female high school and scored 1310 out of 1600 on her SAT.
She was offered the lead in "Buffy the Vampire Slayer" but turned it down.
She won the role that put her on the map with an audition tape shot in her basement.
Her wholesome image was shattered when she appeared nude in a film in 2000.
She has been described as "the Audrey Hepburn of her generation."
Who is she?
The answer at bittenandbound.com

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